Wet Chemicals and Specialty Cleaning

$8,268.00

The Wet Chemicals Report provides a detailed look at the electronic wet chemicals supply chain and market as it applies to semiconductor processing.

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Description

Full table of contents as pdf available here

1   Executive Summary.. 8

1.1   Electronic Wet Chemicals Market Results. 8

1.2   The Worldwide Chemical Industry in Brief 8

1.3   Electronic Chemicals Supply Chain Issues. 11

1.4   Environmental, Health, and Safety. 12

1.5   Market Assessment 13

2 Scope.. 14

  1.  Worldwide Industrial Chemicals Market. 15

3.1 US: Marked by Optimism.. 26

3.1.1   Cost of Manufacturing Wet Chemicals in US.. 29

3.2.  Europe: Sustainability to offer growth opportunities. 31

3.3.  Asia: China is slowing down, but regional growth is solid. 33

4WW High Purity Electronic Wet Chemical Market. 41

4.1   Market Revenues. 42

4.2   Market Overview – Basic Wet Chemicals. 43

4.3   Sulfuric Acid. 44

4.4   Hydrogen Peroxide. 45

4.5   Phosphoric Acid. 46

4.6   HF / BOE products. 48

4.7   Nitric Acid. 49

5Raw Material and Related Supply Chain Issues.. 50

5.1   Hydrochloric Acid (HCI) – Raw Material Supply Chain. 50

5.2   Solvents and the Petrochemical Market 52

5.3   Phosphoric Acid and Phosphor Rock. 53

5.3.1   Phosphor Rock and China. 54

5.3.2   China’s new Rare Earth Policy & impact on the worldwide rare earth industry. 55

5.3.3   The World’s Phosphor Rock Production and Reserves. 57

5.3.4   Phosphor Rock and Low Grade Bulk Phosphoric Acid Price. 59

5.3.5   Phosphoric Acid Usage Worldwide. 60

5.4   HF and the Fluorspar Supply Chain. 62

5.4.1   Fluorspar Trade and Production. 62

6Advanced Cleaning Chemistries- Blends and Advanced Formulations. 66

6.1   Front End of Line Specialty Cleans in Brief 66

6.1.1   Low Temperature EPI 67

6.1.2   Hi K Gate Preclean. 68

6.2   Back End of Line Post-Etch Residue Removal 69

6.2.1   Aluminum Cleans. 69

6.2.2   Copper Cleans. 70

7Materials Opportunities.. 72

7.1   Green Chemistries. 74

7.2 D.I. Water 75

7.3   Pirana Waste Disposal 77

7.4   Blending systems. 80

7.5   Metrology Challenges. 81

7.6   Ge Wet clean. 83

7.7   TiN Wet Etching. 85

7.8   Effect of Additives in HF cleans. 86

8 Post CMP Cleaning.. 87

8.1The post CMP cleaning market overview/dynamics. 88

8.2The pCMP cleaning solutions requirements. 89

8.3New pCMP cleaning chemistries/ solutions. 91

8.3.1Cu pCMP.. 92

8.3.2W pCMP.. 93

8.3.3Ceric pCMP.. 94

8.3.4III-V pCMP.. 94

8.4The pCMP cleaning Market Growth. 95

9 Supply Chain Connections-Makers & Suppliers.. 97

  1. 10. Environmental, Health and Safety.. 99

10.1 US Global Warming Regulation Updates. 99

10.2Chemical Regulations-TSCA reform crossed the finish line. 100

10.3 REACH.. 100

  1. Company Profiles.. 102

11.1 China Suppliers & Makers. 102

    11.1.1 JM (JiangyinJianghua Microelectronics Materials Co), 102

    11.1.2 Jiangyin Runma Electronic Material Co. 103

11.1.3 Rudong Zhenfeng Yiyang Chemical Co., Ltd. (maker) 104

    11.1.4  Bluestar New Chemical Material Co., Ltd. (Maker and Supplier) 105

11.2  Air Liquide (Supplier) 107

11.3  BASF (Maker, Purifier and Supplier) 110

11.4 Dongwoo Fine Chemicals, Ltd. (Korea, Purifier& Supplier) 117

11.5 Dow Chemical (Maker) 118

11.6 Eastman Chemical Company (Maker) 124

11.7 FUJIFILM Ultra Pure Solutions, Inc. (Maker, Purifier & Supplier) 129

11.8 Honeywell International Inc. (Maker, Purifier & Supplier) 133

11.9 Israel Chemicals Ltd. (Maker) – Phosphoric Acid. 137

11.10 Kanto Chemical Co., Inc. (Purifier & Supplier) 139

11.11 KMG Chemicals Inc. (Maker, Purifier & Supplier) 142

11.12 Avantor / Mallinckrodt Baker, Inc. (Purifier & Supplier) 145

11.13 Mitsubishi Gas Chemical Group, Inc. (Maker & Supplier) 146

11.14 One Equity Partners – Peroxychem (Maker) 149

11.15 Solvay* (Maker) 149

Appendix A: China’s 5 Year Plan.. 153

APPENDIX B: Phosphoric Acid Market. 156

Appendix C: Nitric Acid Data on World Consumption.. 158

Appendix D: World’s Phosphor Rock Production and Reserves.. 159

Appendix E: Semiconductor HF/BOE Market Size.. 164

Appendix F: Specialty Cleaning Products – Background.. 171

Appendix G: Wet Chemical Purity Requirements and Trends.. 173

Appendix H: Post CMP Cleans Background.. 175

 

List of Figures

Page #

Figure 1: World Chemical Production at a Glance-2016. 20

Figure 2: World Chemicals Sales by Country: Top 10. 21

Figure 3: World Chemicals Sales by Regions. 22

Figure 4:  International Comparison of Chemical Production Growth by Regions (2005-2015) 23

Figure 5: US Chemical output changes. 27

Figure 6: Fuel, Power and Feedstock Cost as a Percent of Total Costs for Selected Chemical Products. 30

Figure 7: Annual GDP growth for China, India and Developing Asia. 34

Figure 8: Asian Countries’ GDP Comparison. 35

Figure 9: Historical data for China’s GDP Annual growth rate. 37

Figure 10: WW Electronic Wet Chemicals & Specialty Cleaning Chemicals. 43

Figure 11: WW Sulfuric Acid Revenue Estimate ($M’s) 44

Figure 12: WW Hydrogen Peroxide Revenues Estimate ($M’s) 46

Figure 13: WW high Purity Phosphoric Acid Revenues Estimate ($M’s) 47

Figure 14: WW HF/BOE Revenues Estimate ($M’s) 48

Figure 15 WW Nitric Acid Revenues Estimate ($M’s) 49

Figure 16: The World Consumption of Hydrochloric Acid. 51

Figure 17: Worldwide Spot Market Petroleum Price History. 53

Figure 18: China’s new rare earth materials Resource Tax. 56

Figure 19: 2016 Worldwide Phosphor Rock Productions. 59

Figure 20: Phosphor Rock Price Trends. 60

Figure 21: Worldwide Usage of Phosphoric Acid. 61

Figure 22: Worldwide Fluorspar Production 2016. 64

Figure 23: Worldwide Fluorspar Reserves 2016. 65

Figure 24: Growth in Cleaning Volumes/ 66

Figure 25:Photoemission spectra of HF-Passivated Si Surface. 68

Figure 26: High K Logic Gate Structure. 69

Figure 27: Aluminum Cleans Market. 70

Figure 28: WW Copper Cleans Market Revenue Estimate ($M’s) 71

Figure 29: CMP Challenges in 10nm/7nm 76

Figure 30: UPW Usage Billions of Gallons Per Year – Estimate for Total Semiconductor Device Wafer Starts. 77

.Figure 31: Total SPM Waste Millions of Gallons per Year Estimate. 78

Figure 32: Ge Wet Clean NH40H versus. 83

Figure 33: Surface Cleaning Metal REmoval Efficiency on Si and Ge. 84

Figure 34: Wet Cleaning of WF Metals in FinFET. 85

Figure 35: Chelating Agents for Different Metals. 86

Figure 36: Total Revenue for Post CMP Cleans. 87

Figure 37: Post CMP Cleaning Market Shares by % of WW Revenues. 89

Figure 38: Advance Cu Cleaning Mechanism.. 92

Figure 39: Design of EKC Gen IV Cleaner 93

Figure 40: III-V Cleaning and Etching. 95

Figure 41: Annual Wafer Starts. 96

Figure 43:  World Consumption of Nitric Acid. 158

Figure 44: World Phosphoric Acid Capacity Profile (fertilizer grade) 160

Figure 45: China’s Phosphoric Production vs Capacity. 162

Figure 46: World Phosphoric Acid Supply (Production) vs Demand. 162

Figure 47  Basic usages for fluorspar and hydrofluoric acid (HF) 165

Figure 48: Average Acid-Spar Price Trends. 167

Figure 49 CMP Process Steps per Node. 175

 

List of Tables

Table 1: Global Chemical production by Country/Region Percentage Change. 16

Table 2: Global Chemical production by Segment, Percentage Change. 17

Table 3:  Major Chemical Mergers & Acquisitions in 2016. 19

Table 4: C&EN’s Global Top 50 Chemical Companies for 2016. 24

Table 5: Worldwide Chemical Industry Growth. 26

Table 6: Worldwide (WW) High Purity Wet Chemicals Market Ranking. 41

Table 7: Semiconductor Wet Chemical Regional Market Leaders & Market Shares. 42

Table 8: Annual Production of Phosphoric Acid by Region. 62

Table 9: Wet Chemical Suppliers for Selected Chemicals. 98

Table 10: JJM Product Listing. 102

Table 11: Runma Product Listing. 103

Table 12: Air Liquide Sales and Earnings. 108

Table 13: BASF Sales and Earnings. 112

Table 14: Dow Sales and Earnings. 124

Table 15: Eastman Sales and Earnings. 129

Table 16: Honeywell Sales and Earnings. 136

Table 17: ICL Performance Products Group (ICL-PP) Sales and Earnings. 139

Table 18: Kanto’s Ultra Pure Chemicals products list 141

Table 19: KMG Sales and Earnings. 144

Table 20: UltraPure Chemicals/OM Group products lists (Part of KMG) 145

Table 21: Mitsubishi Sales and Earnings. 148

Table 22: The new Solvay Business Structure with Five Operating Segments. 151

Table 23: Solvay Sales and Earnings. 152

Table 24: Aluminum and Copper Clean Product Examples. 171

Table 25: Phosphoric Acid Specification – SEMI Standards – 2013. 174

 

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